Publication details
Transformations of the natural cytokinin N6-isopentenyladenine in aqueous acidic media: structural aspects
| Authors | |
|---|---|
| Year of publication | 2011 |
| Type | Article in Periodical |
| Magazine / Source | Organic and Biomolecular Chemistry |
| MU Faculty or unit | |
| Citation | |
| web | DOI |
| Field | Organic chemistry |
| Keywords | CYCLIN-DEPENDENT KINASES; ADENINE NUCLEOSIDES; POTASSIUM-AMIDE; LIQUID-AMMONIA; DERIVATIVES; INHIBITORS; ADENOSINE; PURINES; COMPLEXES; MECHANISM |
| Description | N6-Isopentenyladenine (L1) was subjected to variously acidic media in 0.1 M, 1 M and 2 M HCl. In dependence on the acidity of the medium, the formation of three main acid hydrolysis products were determined and characterized by multinuclear solution-state NMR spectroscopy and in the solid state by single crystal X-ray analysis. The coordination abilities of these transformation products have been also investigated. |