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Transformations of the natural cytokinin N6-isopentenyladenine in aqueous acidic media: structural aspects
Autoři | |
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Rok publikování | 2011 |
Druh | Článek v odborném periodiku |
Časopis / Zdroj | Organic and Biomolecular Chemistry |
Fakulta / Pracoviště MU | |
Citace | |
www | DOI |
Obor | Organická chemie |
Klíčová slova | CYCLIN-DEPENDENT KINASES; ADENINE NUCLEOSIDES; POTASSIUM-AMIDE; LIQUID-AMMONIA; DERIVATIVES; INHIBITORS; ADENOSINE; PURINES; COMPLEXES; MECHANISM |
Popis | N6-Isopentenyladenine (L1) was subjected to variously acidic media in 0.1 M, 1 M and 2 M HCl. In dependence on the acidity of the medium, the formation of three main acid hydrolysis products were determined and characterized by multinuclear solution-state NMR spectroscopy and in the solid state by single crystal X-ray analysis. The coordination abilities of these transformation products have been also investigated. |