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The DEMS study of electrochemical dehalogenation of aromatic chlorohydrocarbons

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DRBÁLKOVÁ Eva JANDERKA Pavel LOEFFLER Thomas

Rok publikování 2002
Druh Článek ve sborníku
Konference Proceedings of 20th Informal Meeting on Mass Spectrometry
Fakulta / Pracoviště MU

Přírodovědecká fakulta

Citace
Obor Elektrochemie
Klíčová slova Electrodehalogenation cyclic voltammetry mass spectrometry DEMS chlorbenzene
Popis Process of elelectrochemical dehalogenation of aromatic halogenated compounds like chlorobenzene, dichlorobenzenes and chlorotoluene as model halogenated compounds has been studied by means of cyclic voltammetry and on-line mass spectrometry. It has been shown that comparing to direct cathodic electroreduction in nonaqueous solution the dehalogenation process proceeds in aqueous solution at more positive potentials. The electrochemical dehalogenation could be promissing way of transformation of environmentaly hazardous halogenated compounds stored after stopping their usage and production.
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