Project information
Synthesis and properties of inorganic-organic polymeric materials
- Project Identification
- GA203/08/1111
- Project Period
- 1/2008 - 12/2010
- Investor / Pogramme / Project type
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Czech Science Foundation
- Standard Projects
- MU Faculty or unit
- Faculty of Science
- Keywords
- polymeric materials, metallophosphates, metallophosphonates, coordination polymers, porosity, luminescence
The project is aimed at the synthesis of new inorganic-organic polymeric materials and studies of their properties. The syntheses will start from organic derivatives of phosphoric and phosphonic acids, and tertiaary phosphine oxides,, reacting with metal salts and oxides, and from the more complex molecular building units. By hydrothermal and solvothermal methods, hydrolytic and nonhydrolytic condensations and self-assembly driven processes, the precursors will form layered and 3D-framework organic-inorganic hybrid materials and coordination polymers. Their compositions, structures, and physicochemical properties will be studied. The structures will be determined by X-ray diffraction and NMR spectroscopy methods, porosity will be examined by adsorption isotherms of gases, and optical properties will be investigated by time-resolved and steady-state luminescence spectroscopies. The results will serve as a feedback for the modification of starting organic ligands and other molecular precursors in the search for optimal pore characteristics and optical properties of the studied materials.
Publications
Total number of publications: 16
2010
-
Molecular Metallophosphate Precursors for Nonhydrolytic Transformations
MOLMAT 2010 Conference, Montpellier, France, year: 2010
2009
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A Structurally Diverse Series of Aluminum Chloride Alkoxides [ClxAl(m-OR)y]n (R = nBu, cHex, Ph, 2.4-tBu2C6H3)
INORGANIC CHEMISTRY, year: 2009, volume: 48, edition: 17
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Synthesis and structural characterization of new molecular aluminum and yttrium phosphates and phosphonates
Hybrid Materials 2009, year: 2009
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Synthesis and Structural Characterization of New Molecular Titanium and Zirconium Alkoxide Phosphates
Hybrid Materials 2009, year: 2009
2008
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Coordination compounds of lanthanides with polydentate phosphine oxide ligands
VII. SEMINÁR Pokroky v anorganickej chémii, year: 2008
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Luminescence properties of Eu(III) coordination polymers with bis(diphenylphosphino)alkane dioxides
XIXth Slovak-Czech Spectroscopic Conference Book of Abstracts, year: 2008